Investigation on the Photoconductive Properties of MEH-PPV/CdSe Nanocomposite Devices
TANG Ai-wei, TENG Feng*, GAO Yin-hao, JIN Hui, LIANG Chun-jun, XU Zheng, WANG Yong-sheng
Institute of Optoelectronic Technology and Key Laboratory of Luminescence and Optical Information, Ministry of Education, Beijing Jiaotong University, Beijing 100044, China
Abstract:Photoconductive properties of the composite devices made up of cadmium selenide nanocrystals and polymer poly[2-methoxy-5-(2′-ethylhexyloxy-p-phenylenevinylene)](MEH-PPV) were investigated. The photocurrent action spectrum for a nanocomposite device corresponded to the absorption of MEH-PPV and CdSe nanocrystals, indicating that the absorption of the CdSe nanocrystals and MEH-PPV contributed to the photocurrent. The photocurrent was attributed to the exciton dissociation and charge transfer between the interface of CdSe nanocrystals and MEH-PPV. The photocurrent action spectra of the nanocomposite device was wider than that of the pure MEH-PPV device, and the photocurrent was enhanced in comparison with the pure MEH-PPV device due to the introduction of CdSe nanocrystals.
[1] Sariciftci N S. Primary Photoexcitations in Conjugated Polymers: Molecular Exciton Versus Semiconductor Band Model. London: World Scientific, 1997. 37. [2] JIN Hui, TENG Feng, LIU Jun-feng, et al(靳 辉,滕 枫,刘俊峰, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2004,24(8): 918. [3] Greenham N C. Peng X, Alivisatos A P. Phys. Rev. B, 1996, 54: 17628. [4] Huynh W U, Peng X , Alivisatos A P. Adv. Mater., 1999, 11: 923. [5] Mcdonald S A, Cyr P C, Levina L, et al. Appl. Phys. Let., 2004, 85: 2089. [6] Winiarz J G, Zhang L M, Lal M, et al. Chem. Phys., 1999, 245: 17. [7] Wang Y, Herron N. J. Luminescence., 1996, 70: 48. [8] Wang S H, Yang S H, Yang C L, et al. J. Phys. Chem.B, 2000, 104: 11853. [9] Peng Z A, Peng X G. J. Am. Chem. Soc., 2001, 123: 183. [10] Sharma Shailendra Sharma G D, Roy M S. J. Mater. Sci.: Mater in Electronics, 2004, 15: 69. [11] Colvin V L, Schlamp M C, Alivisatos A P. Nature, 1994, 370: 354. [12] Coe S, Woo W K, Bawendi M. Nature, 2002, 420: 800.