Abstract:Based on the color reaction of 2-(2-quinolinylazo)-5-diethylaminoaniline (QADEAA) with palladium(Ⅱ) and the solid phase extraction of its colored complex with MCI-GEL reversed phase cartridge, a new method for the determination of trace palladium was established. In the presence of 0.2-2.0 mol·L-1 of hydrochloric acid solution and CTMAB medium, QADEAA reacts with palladium(Ⅱ) to form a stable 2∶1 complex. The colored complex can be enriched by MCI-GEL reversed phase cartridge, and the retained chelates was then eluted by acetone. The eluant was determined by spectrophotometry at 615 nm. Beer’s law is obeyed in the range of 0.01-1.5 mg·L-1. This method was applied to the determination of palladium with good results.
[1] YANG Xiang-zhen(杨乡珍). Chinese Journal of Geology Laboratory(地质实验室), 1992,8(1):42. [2] DONG Hui-ru,L Kun(董慧茹,吕 琨). Chinese Journal of Physical Testing and Chemical Analysis(Chemical Analysis, Part B)(理化检验·化学分册), 1998,34(6):277. [3] HU Qiu-fen, HUANG Zhang-jie, DONG Xue-chang, et al. Turkish Journal of Chemistry, 2005, 29(2): 261. [4] YANG Bo,ZHOU Li-qiong,YIN Jia-yuan(羊 波,周丽琼,尹家元). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2004,24(9):1110. [5] WANG Lin,HU Qiu-fen,YANG Guang-yu,et al(王 琳,胡秋芬,杨光宇,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2004, 24(2): 187. [6] TAI Xi,HU Qiu-fen,YANG Guang-yu, et al(台 希,胡秋芬,杨光宇,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2004, 24(1): 125. [7] Yang Guangyu, Huang Zhangjie, Hu Qiufen, et al. Talanta, 2002, 58(3): 511. [8] Amarowicz R, Shahidi F. Food Research International, 1996, 29(1): 71. [9] Froytlog C, Slimestad R, Andersen M. Journal of Chromatography A, 1998, 825(1): 89. [10] L Jie-li,YANG Zhong-han, YUAN Ke(吕洁丽,杨中汉,袁 珂). Journal of Chinese Medicinal Materials(中药材), 2005,28(3): 239. [11] Edited by Chinese Enviromment Protection Agency(国家环保局编). Analysis Method for Monitoring Water and Waste Water,Third Edition(水和废水监测分析方法·第3版). Beijing:Chinese Environmental Science Press(北京:中国环境科学出版社),1989. 21. [12] FANG Yi-wen, DONG Xin-fa, XUE Liang, et al(方奕文,董新法,薛 亮,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2006,26(10):1912.