微波法合成红色长余辉发光材料Gd<SUB>2</SUB>O<SUB></SUB>2S∶Eu, Mg, Ti及其发光特性

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摘要：用微波辐射法首次合成了Gd₂O₂S∶Eu，Mg，Ti 红色磷光化合物，用X射线粉末衍射(XRD)、扫描电镜(SEM)、荧光分光光度计等对合成产物进行了分析和表征。结果表明：材料的晶体结构为六方晶系，与Gd₂O₂S的相同。颗粒的形貌为类球形，分散性较好，尺寸在1～2 μm之间。Gd₂O₂S∶Eu，Mg，Ti 的激发光谱呈带状，激发光谱主峰位于360 nm，另外在400, 422, 472 nm等处也有激发峰存在；发射光谱为线状光谱，归属于Eu³⁺的⁵D_J(J=0, 1, 2)到⁷F_J(J=0, 1, 2, 3, 4)的跃迁。随着Eu浓度的增加，位于蓝绿区的586, 557, 541, 513, 498, 471, 468 nm 处的发射峰逐渐减弱，而主峰位于627 nm处的红光发射明显增强。当Eu浓度为6 mol%时，红光发射最强。Mg, Ti共掺杂可显著改善其余辉性质。

关键词：Gd₂O₂S∶Eu;Mg;Ti;微波法;激发光谱;发射光谱;长余辉

Abstract：Gd₂O₂S∶Eu, Mg, Ti, a novel red long afterglow phosphor, was synthesized in microwave field. The synthesized phosphors were investigated respectively by XRD, SEM and fluorescence spectrophotometer. The results show that Gd₂O₂S∶Eu, Mg, Ti phosphors possess hexagonal crystal structure, which is similar to that of Gd₂O₂S. The particles of Gd₂O₂S∶Eu, Mg, Ti phosphors are basically spherical in shape，with good dispersing. The mean particle size is 1-2 μm. The excitation spectrum is a broad band and the main peak is at 360 nm. Moreover, excitation peaks at 400, 422 and 472 nm were found in the excitation spectrum. The emission spectrum shows that Gd₂O₂S∶Eu, Mg, Ti has narrow emission peaks. The emission peaks are ascribed to Eu³⁺ ions transition from 5D_J(J= 0, 1, 2) to ⁷F_J(J=0, 1, 2, 3, 4). With the increase in Eu³⁺ molar ratio, the emission peaks at 586, 557, 541, 513, 498, 471 and 468 nm in the blue and green region weaken gradually relative to the main emission peak at 627 nm. Therefore the red emitting at 627 nm becomes strong gradually. When the molar ratio is 6%, the red emitting becomes the strongest. The Ti and Mg co-doping can obviously improve its long-afterglow property.

Key words：Gd₂O₂S∶Eu;Mg;Ti;Microwave method;Excitation spectrum;Emission spectrum;Long afterglow

收稿日期: 2005-12-14 修订日期: 2006-06-28

中图分类号:

O614.3

通讯作者: 翟永清 E-mail: zhaiyongqinghbu@163.com

引用本文:

翟永清,刘元红,孟媛,张少阳. 微波法合成红色长余辉发光材料Gd₂O2S∶Eu, Mg, Ti及其发光特性[J]. 光谱学与光谱分析, 2007, 27(04): 634-638.
ZHAI Yong-qing,LIU Yuan-hong,MENG Yuan,ZHANG Shao-yang. Synthesis of the Red Long Afterglow Phosphor Gd₂O₂S∶Eu, Mg, Ti by Microwave Radiation Method and Its Luminescent Properties . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(04): 634-638.

链接本文:

https://www.gpxygpfx.com/CN/Y2007/V27/I04/634

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