Application of X-Ray Fluorescence Spectrometry in Geological and
Mineral Analysis for 60 Years
LI Xiao-li1, WANG Yi-min2*, DENG Sai-wen2, WANG Yi-ya2, LI Song2, BAI Jin-feng1
1. Institute of Geophysical and Geochemical Exploration, Chinese Academy of Geological Sciences, Langfang 065000, China
2. National Research Center for Geoanalysis, Beijing 100037, China
Abstract:As the earliest application field of X-ray fluorescence spectroscopy technology in China, geology and mineral resources application has also been introduced and developed for 60 years. This article introduces the establishment and early development of an X-ray fluorescence spectroscopy laboratory in China. This paper summarizes the main time nodes and important events for the introduction and development of modern X-ray spectroscopic analysis technology in geological and mineral resources systems in the 1980s, including technical preparation, the introduction of instrumentation and software, Mr G R Lachance, Geological Survey of Canada, Dr Philips de Jongh and other famous scholars were invited to give lectures in China and the support of the China-Germany (Federal Institute of Geology and Raw Materials) two phases of cooperation projects. It focuses on the application of modern X-ray fluorescence branch technology (including portable X-ray fluorescence, synchrotron radiation X-ray fluorescence, scanning nuclear probe, fully reflection X-ray fluorescence and microbeam X-ray fluorescence, etc.) in the field of geoscience, the main achievements and the important contributions to the geological and mining industry, Including silicate rock full analysis, trace and ultra-light element analysis, all kinds of ore analysis, geochemical investigation and international geochemical mapping sample analysis, Marine geology and mineral resources survey field analysis, rare earth elements, halogen element analysis, field analysis, in situ microanalysis and standard material development and standard analysis methods of 11 applications. Especially in the 1980s, it realized the X-ray fluorescence method of “alternative” to the traditional chemical method and became the leading method of full rock analysis, fundamentally changed the face of geological analysis in China, strongly promoted the development of modern earth science, and become a milestone in the development of geological analysis technology in China. In the analysis of 100 million samples of large-scale geochemical survey and international geochemical mapping project, the X-ray fluorescence analysis method give full play to the sample of simple, fast, economical and pollution-free advantages, becoming a variety of analysis methods supporting the leading technology, thus mading an unprecedented outstanding contribution. The former method has a typical significance in the geological analysis of China today, representing the general level of the conventional geological analysis of China today, and has the characteristics of The Times. Finally, the future development of the geoscience application of X-ray fluorescence spectrometry was prospected. There were 64 citations in the paper.
Key words:X-ray fluorescence spectroscopy; Application; Geology and mineral;Development;History
李小莉,王毅民,邓赛文,王祎亚,李 松,白金峰. 中国X射线荧光光谱分析的地学应用60年[J]. 光谱学与光谱分析, 2023, 43(10): 2989-2998.
LI Xiao-li, WANG Yi-min, DENG Sai-wen, WANG Yi-ya, LI Song, BAI Jin-feng. Application of X-Ray Fluorescence Spectrometry in Geological and
Mineral Analysis for 60 Years. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 2989-2998.
[1] WANG Yi-min, WANG Xiao-hong(王毅民, 王晓红). Rock and Mineral Analysis(岩矿测试), 2000,19(4): 275.
[2] WANG Yi-min, DENG Sai-wen, WANG Yi-ya, et al(王毅民, 邓赛文, 王祎亚, 等). Metallurgical Analysis(冶金分析), 2020, 40(10): 32.
[3] LU Yun-jin(卢云锦). Fluorescence X-Ray Spectroscopy(荧光X-射线光谱分析). Report of the Annual Meeting of National Test Bases (Part Ⅱ) [全国测试基地年会报告集(下集)]. Beijing: State Science and Technology Commission(北京: 国家科委), 1964, 48.
[4] Institute of Geological Sciences(地质科学研究院). Geological Science and Technology, Supplement (Experimental Work)[地质科技,增刊(实验工作)]. Beijing: Geological Publishing House(北京:地质出版社), 1973.
[5] XIE Zhong-xin, ZHAO Zong-ling, ZHANG Yu-bin, et al(谢忠信,赵宗玲,张玉斌,等). X-Ray Spectral Analysis(X射线光谱分析) Beijing: Science Press(北京: 科学出版社),1982, 582.
[6] ZHANG Yu-bin, CAO Zhen-qian, JIANG Hui-zhong(张玉斌,曹振乾,蒋惠鐘). Fluorescence X-Ray Spectroscopy, Emission Spectroscopy and Chemical Combined Rock Analysis(荧光X光谱、发射光谱、化学联合岩石全分析) . Proceedings of the National Rock and Mineral Analysis Experience Exchange Conference(全国岩矿分析经验交流会文集). Beijing: Science Press(北京:科学出版社), 1976, 517.
[7] LIU Zhen-rong, CHEN Yong-jun, ZHAO Zong-ling(刘珍荣,陈永军,赵宗玲). Analysis of Silicate Rock Samples by X-Ray Fluorescence Spectrometry (X射线荧光光谱分析硅酸盐岩石样品). Edited by the Editorial Office of Books and Periodicals of the Ministry of Geology and Mineral Resources, Proceedings of the 1980 National Rock and Mineral Analysis Experience Exchange Meeting(地质矿产部书刊编辑室编辑,一九八零年全国岩矿分析经验交流会论文集). Beijing: Geological Publishing House(北京:地质出版社), 1982,12.
[8] Institute of Geology and Mineral Resources(中国地质科学院地质矿产所). Chinese Academy of Geological Sciences, 1976. Foreign Geological References 7: X-Ray Fluorescence Analysis of Light Elements in Rocks and Minerals(国外地质参考资料7:岩石矿物中轻元素的X射线荧光分析专辑). Beijing: Institute of Geology and Mineral Resources, Chinese Academy of Geological Sciences(北京: 中国地质科学院地质矿产所), 1976, 360.
[9] ZHAO Zong-ling, LIU Zhen-rong, DIAO Gui-nian(赵宗玲, 刘珍荣,刁桂年). Translation Collection of X-Ray Fluorescence Analysis——Mathematical Correction Method and Application of New Technology(X射线荧光分析译文集——数学校正法及新技术的应用). Beijing: Geological Publishing House(北京: 地质出版社), 1981, 231.
[10] Birks L S. X-Ray Spectral Analysis(X射线光谱分析). Translated by GAO Xin-hua(高新华,译). Beijing: Metallurgical Industry Press(北京:冶金工业出版社), 1973, 131.
[11] Афонин В П,Гфуничева Т Н. X-Ray Fluorescence Spectral Analysis of Rocks and Minerals(岩石矿物的X射线荧光光谱分析). Translated by SONG Ji-ren,ZHOU Guo-qing(宋吉人,周国清,译). Beijing: Geological Publishing House(北京:地质出版社), 1980, 221.
[12] ZHANG Jia-hua, XU Jun-quan, ZHU Jie-qing(张家骅,徐君权,朱节清). Radioisotope X-Ray Fluorescence Analysis(放射性同位素X射线荧光分析). Beijing: Atomic Energy Press(北京: 原子能出版社), 1981,388.
[13] Bertin E P. Introduction to X-Ray Spectral Analysis(X射线光谱分析导论). Translated by GAO Xin-hua(高新华, 译). Beijing: Geological Publishing House(北京:地质出版社), 1981, 457.
[14] Bertin E P. Principle and Application of X-Ray Spectral Analysis(X射线光谱分析的原理和应用). Translated by LI Rui-cheng, BAO Yong-fu,WU Xiao-lin(李瑞诚,鲍永夫,吴效林,译). Beijing: National Defense Industry Press(北京: 国防工业出版社), 1983, 602.
[15] FENG De-you(冯德友). Chemical Reagents(化学试剂), 1988, (6): 371.
[16] LI Yan-cheng, LI Nai-zhen(李彦成, 李乃珍). Cement(水泥), 1979, (2): 13.
[17] DIAO Gui-nian, CHEN Pi-tong, LI Jin-xun, et al(刁桂年, 陈丕通, 李锦勋,等). Chinese Journal of Analytical Chemistry(分析化学), 1983,(1): 45.
[18] WANG Yi-ya, DENG Sai-wen, WANG Yi-min, et al(王祎亚, 邓赛文, 王毅民, 等). Metallurgical Analysis(冶金分析), 2020, 40(10): 12.
[19] Raschka H, Lodziak J, LI Guo-hui, et al(Raschka H, Lodziak J, 李国会, 等). Chinese Journal of Analytical Chemistry(分析化学), 1982,(10): 609.
[20] MA Guang-zu, LI Guo-hui(马光祖, 李国会). Physical Testing and Chemical Analysis(Part B: Chemical Analysis)(理化检验-化学分册),1983,19(4): 18.
[21] LI Guo-hui, LIU De-hui, SU You-luan(李国会, 刘德慧, 苏幼銮). Geophysical and Geochemical Exploration(物探与化探), 1986, 10(1): 60.
[22] XU Ji-rong, WU Zhi-hong, LE Qun, et al(徐积荣, 吴志鸿, 乐 群, 等). Rock and Mineral Analysis(岩矿测试), 1986,(3): 201.
[23] SU You-luan, WANG Yi-min(苏幼銮,王毅民). Rock and Mineral Analysis(岩矿测试), 1988,7(2): 112.
[24] LI Jia-xi, ZHU Yu-lun(李家熙,朱玉伦). Rock and Mineral Analysis(岩矿测试), 1990, 9(1): 1.
[25] JI Ang, YUAN Ning-er(吉 昂, 袁宁儿). Chinese Journal of Analytical Chemistry(分析化学), 1990, (11): 1025.
[26] REN Hong-xing, HE Chun-fu, ZHANG Qi-chao(任红星, 贺春福, 张启超). Chinese Journal of Analysis Laboratory(分析试验室), 1991,(6): 44.
[27] LUO Li-qiang, MA Guang-zu, JI Ang(罗立强, 马光祖, 吉 昂). Chinese Journal of Analytical Chemistry(分析化学), 1992,(9): 1074.
[28] LIANG Guo-li, LUO Li-qiang(梁国立, 罗立强). Rock and Mineral Analysis(岩矿测试), 1993, (11): 35.
[29] LUO Li-qiang, GUO Chang-lin, JI Ang, et al(罗立强, 郭常霖, 吉 昂, 等). Rock and Mineral Analysis(岩矿测试), 1997,(2): 128.
[30] LUO Li-qiang, MA Guang-zu, JI Ang, et al(罗立强, 马光祖, 吉 昂,等). Journal of Analytical Science(分析科学学报), 1998, (3): 177.
[31] LUO Li-qiang, GAN Lu, WU Xiao-jun, et al(罗立强, 甘 露, 吴晓军,等). Chinese Journal of Analysis Laboratory(分析试验室), 2001, (1): 1.
[32] LUO Li-qiang, LIANG Guo-li, MA Guang-zu, et al(罗立强, 梁国立, 马光祖, 等). Journal of Analytical Science(分析科学学报), 1996,(3): 189.
[33] CHEN Yong-jun, XU Li, HUA You-nan(陈永君, 许 力, 华佑南). Rock and Mineral Analysis(岩矿测试), 1988, 4: 327.
[34] CHEN Yong-jun(陈永君). Rock and Mineral Analysis(岩矿测试), 1991, 3: 232.
[35] GB/T 14506.28—1993(2010) Methods for Chemical Analysis of Silicate Rocks-Part 28: Determination of 16 Major and Minor Elements Content[GB/T 14506.28—1993(2010) 硅酸盐岩石化学分析方法 第28部分: 16个主次成分量测定]. General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, China National Standardization Administration Committee(中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会). Beijing: China Standards Press(北京:中国标准出版社),1993 (2010).
[36] ZHENG Hou-lin(郑厚琳). Non Ferrous Minerals and Exploration(有色金属矿产与勘查), 1997, S1: 67.
[37] WANG Yi-ya, ZHAN Xiu-chun, et al(王祎亚, 詹秀春, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2014, 34(4): 1118.
[38] WANG Jian-qi, LIU Xiao-ming, et al(王建其, 柳小明, 等). Rock and Mineral Analysis(岩矿测试), 2016,35(2): 145.
[39] WANG Xiao-hong, HE Hong-liao, WANG Yi-min, et al(王晓红, 何红蓼, 王毅民, 等). Journal of Instrumental Analysis(分析测试学报), 2010,29(6): 578.
[40] LIU Zhi-peng, WANG Rong-she, LI Zhi-tao, et al(刘智鹏, 王荣社, 李智涛, 等). Chinese Journal of Inorganic Analytical Chemistry(中国无机分析化学), 2013, 3(4): 27.
[41] WANG Yi-ya, WANG Yi-min, GAO Xin-hua, et al(王祎亚, 王毅民, 高新华, 等) . Metallurgical Analysis(冶金分析), 2020, 40(10): 1.
[42] LI Song, DENG Sai-wen, WANG Yi-min, et al(李 松,邓赛文,王毅民, 等). Metallurgical Analysis(冶金分析), 2021,41(3):18.
[43] LI Xiao-li, DENG Sai-wen, WANG Yi-min, et al(李小莉, 邓赛文,王毅民,等). Metallurgical Analysis(冶金分析), 2022,42(3):33.
[44] WANG Yi-min, WANG Xiao-hong, GAO Yu-shu(王毅民, 王晓红, 高玉淑). Advance in Earth Sciences(地球科学进展), 2003,18(3): 476.
[45] ZHOU Guo-hua(周国华). Rock and Mineral Analysis(岩矿测试), 2010, 29(3): 296.
[46] WANG Yi-min, DENG Sai-wen, LI Song, et al(王毅民, 邓赛文, 李 松, 等). Metallurgical Analysis(冶金分析), 2020, 40(10): 50.
[47] WANG Yi-min(王毅民). Rock and Mineral Analysis(岩矿测试), 1992,11(1/2): 179.
[48] WANG Xiao-hong, WANG Yi-min, ZHANG Xue-hua(王晓红, 王毅民, 张学华). Acta Geoscientica Sinica(地球学报), 2002, 23(1): 7.
[49] CHEN Dao-hua, DIAO Shao-bo, ZHANG Xin(陈道华, 刁少波, 张 欣). Rock and Mineral Analysis(岩矿测试), 2013, 32(6): 850.
[50] WANG Yi-min, ZHANG Xue-hua, DENG Sai-wen, et al(王毅民, 张学华, 邓赛文, 等). Metallurgical Analysis(冶金分析), 2020, 40(10): 63.
[51] JING Zhao-zheng, ZHANG Bo-yi(荆照政, 张博仪). Physical Testing and Chemical Analysis Part B: Chemical Analysis(理化检验: 化学分册), 1989, 25(6): 355.
[52] ZHOU Wei, ZENG Meng, WANG Jian, et al(周 伟, 曾 梦, 王 健, 等). Rock and Mineral Analysis(岩矿测试), 2018,37(3): 298.
[53] WANG Yi-ya, GAO Xin-hua, WANG Yi-min, et al(王祎亚, 高新华, 王毅民, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2020, 40(11):3341.
[54] LIU De-hui, AN Qing-xiang(刘德慧, 安庆骧). Rock and Mineral Analysis(岩矿测试), 1988, (4): 271.
[55] WANG Yi-min, HE Zhong-yang(王毅民,贺中央). Chinese Journal of Analytical Chemistry(分析化学), 1989,17(1):87.
[56] LI Xiao-li, GAO Xin-hua, WANG Yi-min, et al(李小莉, 高新华,王毅民,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2022, 42(4): 997.
[57] DENG Sai-wen, LI Song, WANG Yi-min, et al(邓赛文, 李 松, 王毅民, 等) . Metallurgical Analysis(冶金分析), 2020,40(10): 76.
[58] GE Liang-quan, LI Fei(葛良全,李 飞). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2021, 41(3): 704.
[59] WANG Yi-ya, GAO Xin-hua, WANG Yi-min, et al(王祎亚, 高新华, 王毅民, 等). Metallurgical Analysis(冶金分析), 2020, 40(10): 86.
[60] WANG Yi-ya, WANG Yi-min, DENG Sai-wen, et al(王祎亚,王毅民,邓赛文,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2020,40(6):1728.
[61] WANG Yi-min, CHEN You-ping(王毅民, 陈幼平). Geological Review(地质论评), 2008,54(5): 653.
[62] WANG Yi-ya, ZHANG Zhong, WANG Yi-min, et al(王祎亚, 张 中, 王毅民, 等). Metallurgical Analysis(冶金分析), 2020, 40(10): 99.
[63] WANG Yi-ya, WANG Yi-min(王祎亚,王毅民). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2021, 41(3):696.