Abstract:Qi and Huai chrysanthemum samples processed in different ways were discriminated by means of Fourier transform infrared (FTIR) spectroscopy. It was shown that different processing methods may result in the variation of relative content of effective components in chrysanthemum. The variation of chemical structure may also occur. And the variations can be reflected differently on the transform infrared spectra. The dry chrysanthemum smoked with sulphur had different characters in the vibration frequency and shape of IR from other samples at 1 600 and 1 060 cm-1,and showed static characteristic absorptions at 922, 818 and 777 cm-1,which were stronger than others. The chrysanthemum processed in different ways showed differences in the Fourier transform infrared spectra. The sulphur residue in chrysanthemum can be identified by FTIR without separation and abstraction. This method is not only quick and precise but also convenient and direct. Different sorts of chrysanthemum can be identified in this way.
[1] ZHANG Gui-jun(张贵君). Identification of Chinese Tradition Drugs(常用中药鉴定大全). Haerbin: Heilongjiang Science and Technology Press(哈尔滨: 黑龙江科学技术出版社), 1997. [2] WANG Zhao-ji, GUAN Xi-yao, WANG Jie, et al(王兆基, 关锡耀, 汪 洁, 等). Chinese Traditional and Herbal Drugs(中草药), 2000, 31(2): 97. [3] ZHAO Hua-rong, WEN Shu-min, WANG Xiao-yan, et al(赵花荣, 温树敏, 王晓燕, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2005, 25(5): 705. [4] GUO Ping, XIONG Ping, YUAN Ya-li(郭 萍, 熊 平, 袁亚莉). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2002,22(4):603. [5] SUN Su-qin, ZHOU Qun, LIANG Xi-yun, et al(孙素琴, 周 群, 梁曦云, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2002,22(4):600. [6] ZHOU Qun,LI Jing, SUN Su-qin, et al(周 群,李 静,孙素琴,等). Chinese J. Anal. Chem.(分析化学), 2003, 31(3): 292. [7] XIE Jing-xi, CHANG Jun-biao, WANG Xu-ming(谢晶曦, 常俊标, 王绪明). The Application of Infrared Spectroscopy in Organic and Drug Chemistry(红外光谱在有机化学和药物化学中的应用). Beijing: Science Press(北京: 科学出版社), 1987.