中国微束X射线荧光分析技术应用评介

doi:10.3964/j.issn.1000-0593(2020)06-1728-08

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摘要：简述了X射线荧光（XRF）分析与微束X射线荧光（MXRF）分析的技术特点、仪器构成、应用领域和工作范围。从准直的微束X射线荧光、整体X射线荧光与微束X射线荧光组合、波谱/能谱多功能组合和毛细管X光会聚透镜微束X射线荧光仪器四类仪器评介了中国微束X射线荧光仪器和分析技术的应用与发展。从分析功能定位和技术发展两方面，展望了微束X射线荧光技术的发展。提出将XRF分析中传统的微束原位（微区）XRF（MXRF）分析进一步区分为“微-纳区分析（μ/n-XRF）”和“微-毫区分析（μ/m-XRF）”，如此区分该项技术及适用范围定位，对两者原位分析技术的发展都是有益的，特别也明确定位说明了整体/微区组合仪器的功能和适用范围发展与应用。作者强调：原位（微区）分析并非仅为单纯的分析工作，更重要的在于对被测样品特性的研究与结果解读！分析人员和专业科学家的密切合作，才能充分发挥原位微区分析技术的效能，充分解读展现分析结果的科学意义。

关键词：X射线荧光；微束X射线荧光（MXRF）；多功能仪器；微-纳区分析（μ/n-XRF）；微-毫区分析（μ/m-XRF）

Abstract：The technical characteristics, instrument composition, application fields and working scope of X-ray fluorescence （XRF）and micro-X-ray fluorescence analysis （MXRF）are briefly described. The development of micro-X-ray fluorescence instruments and analytical techniques in China is reviewed from four aspects: collimated microbeam X-ray fluorescence instrument, integrated X-ray fluorescence and micro-X-ray fluorescence instrument, micro-X-ray fluorescence function in multifunctional (spectrum/energy spectrum) instrument and capillary X-ray convergent lens micro-X-ray fluorescence instrument. Finally, the development of micro-X-ray fluorescence technology has prospected from two aspects of functional positioning and technological development. It is proposed that the traditional in-situ microanalysis can be further divided into “μ-n(area)-analysis(μ-XRF)” and “sub-mm-cm(area)-analysis(MXRF)”. This kind of technical distinction and application scope positioning is beneficial to the development of in-situ microanalysis technology, and also provides a clear positioning for the development and application of integrated/micro-zone combination instruments. The author also emphasizes that in-situ microanalysis is not a simple analytical problem, but more importantly, the study of the properties of the tested materials and the reasonable interpretation of the results. Close cooperation between analytical technicians and professional scientists can give full explain to the effectiveness of in-situ analytical techniques and analyze the scientific significance of analytical results in detail.

Key words：X-ray fluorescence; Micro-X-ray fluorescence; Multi-functional instrument; μ-n(area)-analysis(μ-XRF); μ-m(area)-analysis(MXRF)

收稿日期: 2019-05-06 修订日期: 2019-09-20

中图分类号:

O657.34

基金资助: 国家自然科学基金项目（41371212，40902055），国家重大科学仪器设备开发专项（2012YQ050076）资助

通讯作者: 王毅民 E-mail: 10.3964/j.issn.1000-0593(2020)06-1728-08

作者简介: 王祎亚，1978年生，国家地质实验测试中心高级工程师 e-mail: yiyawang@163.com

引用本文:

王祎亚，王毅民，邓赛文，高新华，梁国立，张中. 中国微束X射线荧光分析技术应用评介[J]. 光谱学与光谱分析, 2020, 40(06): 1728-1735.
WANG Yi-ya, WANG Yi-min, DENG Sai-wen, GAO Xin-hua, LIANG Guo-li, ZHANG Zhong. Review on the Application of Micro-X-Ray Fluorescence Analysis Technology in China. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(06): 1728-1735.

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[1] Adler I, Axelrod J. Advance in X-Ray Analysis, 1958, 2: 167.
[2] Heinrich K H J. Advance in X-Ray Analysis, 1961, 5: 515.
[3] Nichols M C, Ryon R W. Advances in X-Ray Analysis, 1986, 29: 423.
[4] Boehme D R. Advances in X-Ray Analysis, 1987, 30: 39.
[5] Kumakhov M A, Komarov F F. Physics Reports, 1990, 191(5) : 289.
[6] DING Xun-liang, LIANG Wei, YAN Yi-ming(丁训良, 梁炜, 颜一鸣). Nuclear Techniques(核技术), 1996, 19(3): 164.
[7] WANG Kai-ge, WANG Lei, NIU Han-ben(王凯歌, 王雷, 牛憨笨). J. Appl. Opt.(应用光学), 2008, 29(2): 183.
[8] ZHU Jie-qing, LE An-quan, GU Ying-mei, et al (朱节清, 乐安全, 谷英梅, 等). Gold Sci. Technol.(黄金科学技术), 2004, (6): 26.
[9] CHAO Zhi-yu, WU Ying-rong, LIU Gong-zhun, et al(巢志瑜, 吴应荣, 刘功谆, 等). Rock Min. Anal.（岩矿测试）, 1990, (3): 161.
[10] Beijing Shimadzu Scientific Instrument Center(北京岛津科学仪器中心). Modern Instrument(现代仪器), 2003, (5): 40.
[11] WANG He-quan, WU Li-jun(王鹤泉, 吴立军). Seventh Annual Conference of Analytical Chemistry and Academic Conference on Atomic Spectroscopy of the Chinese Chemical Society(中国化学会第七届分析化学年会暨原子光谱学术会议论文集), 2002. 1424.
[12] ZHAO Hong-qiao, ZHENG Cun-jiang, CHU Feng-you, et al(赵宏樵, 郑存江, 初凤友, 等). J. Marin. Sci.(海洋学研究), 2009, 27(2): 84.
[13] XU Ben-ping, ZHONG Hua, ZHOU Ming, et al(徐本平, 钟华, 周铭, 等). Metal. Anal.(冶金分析), 2009, 29(11): 19.
[14] LIANG Shu-ting, LIU Yu-chun, LIU Zhen, et al(梁述廷, 刘玉纯, 刘瑱, 等). Rock Min. Anal.(岩矿测试), 2013, 32(6): 897.
[15] LIANG Shu-ting, LIU Yu-chun, LIU Zhen, et al(梁述廷, 刘玉纯, 刘瑱, 等). Rock Min. Anal.(岩矿测试), 2015, 34(2): 201.
[16] Panalytical(帕纳科). Zetium User Guide(Zetium用户指南), 2015.
[17] YANG Li-hui, ZHENG Xiang-min, YE Wei(杨立辉，郑祥民，叶玮). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2017, 37(6)：1955.
[18] XIE Jin-dong, DING Xun-liang, HE Ye-jun, et al(谢晋东, 丁训良, 赫业军, 等). Journal of BeiJing Normal University·Natural Science(北京师范大学学报·自然科学版), 1999, 35(1): 46.
[19] DING Xun-liang, PAN Qiu-li, LIU Zhi-guo, et al(丁训良, 潘秋丽, 刘志国, 等). Journal of Beijing Normal University·Natural Science(北京师范大学学报·自然科学版), 2004, (5): 634.
[20] SUN Tian-xi, LIU He-he, LIU Zhi-guo, et al(孙天希, 刘鹤贺, 刘志国, 等). Acta Optica Sinica(光学学报), 2014, 1: 0134001.
[21] LI Fang-zuo, LIU Zhi-guo, SUN Tian-xi, et al(李坊佐, 刘志国, 孙天希, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2015, 35(9): 2487.
[22] CHU Xue-lian, LIN Xiao-yan, CHENG Lin, et al(初学莲, 林晓燕, 程琳, 等). Journal of Beijing Normal University·Natural Science(北京师范大学学报·自然科学版), 2007, (5): 530.
[23] CHU Xue-lian, LIN Xiao-yan, CHENG Lin, et al(初学莲, 林晓燕, 程琳, 等). Nucl. Phys. Rev.(原子核物理评论), 2008, (1): 61.
[24] CHENG Lin, PAN Qiu-li, DING Xun-liang, et al(程琳, 潘秋丽, 丁训良, 等). Atom. Energ. Sci. Technol.(原子能科学技术), 2008, (1): 1.
[25] SUN Tian-xi, XU Guang-yu, LIU Zhi-guo, et al(孙天希, 徐光瑜, 刘志国, 等). Acta Optica Sinica(光学学报), 2008, 9: 1833.
[26] SUN Tian-xi, LIU Zhi-guo, LI Yu-de, et al(孙天希, 刘志国, 李玉德, 等). Acta Optica Sinica(光学学报), 2011, 4: 303.
[27] GE Liang-quan, SUN Chuan-min, GU Yi, et al(葛良全, 孙传敏, 谷懿, 等). J. Mineralogy Petrology(矿物岩石), 2010, 3: 105.
[28] SONG Wei-jie, GE Liang-quan, YANG Jian, et al(宋卫杰, 葛良全, 杨健, 等). Nuclear Electronics & Detection Technology(核电子学与探测技术), 2009, (4): 828.
[29] YANG Wen-jia, GE Liang-quan, LUO Bin, et al(杨文佳, 葛良全, 罗斌, 等). Chinese Journal of Spectroscopy Laboratory(光谱实验室), 2013, (6): 2779.
[30] LUO Li-qiang, SHEN Ya-ting, MA Yan-hong, et al(罗立强，沈亚婷，马艳红，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2017, 37(4)：1003.
[31] Shimadzu (Hong Kong) Limited Beijing Representative Office(岛津（香港）有限公司北京代表处). Modern Scientific Instruments(现代科学仪器), 2003, (3): 78.
[32] XU Che, LUO Yi-wen, YANG Xu, et al(徐彻, 罗仪文, 杨旭, 等). Chin. J. Foren. Sci.(中国司法鉴定), 2008, (2): 21.
[33] HU Sun-lin, SHEN Hui, David Lie, et al(胡孙林, 沈辉, 戴维列, 等). J. Instr. Anal.(分析测试学报), 2009, (7): 824.
[34] HU Sun-lin, WEN Jin-feng, LAI Wen-bin, et al(胡孙林, 温锦锋, 赖文彬, 等). J. Foren. Med.(法医学杂志), 2010, (4): 257.
[35] LI Qian, WEN Jin-feng, LIN Xian-wen, et al(黎乾, 温锦锋, 林贤文, 等). J. Instr. Anal.(分析测试学报), 2015, (4): 453.
[36] LI Li, ZHANG Jian-hua, LUO Yi-wen, et al(李立, 张建华, 罗仪文, 等). Chinese J. Foren. Med.(中国法医学杂志), 2011, 26(1): 1.
[37] SU Hui-fang, LIU Chao, HU Sun-lin, et al(苏会芳, 刘超, 胡孙林, 等). J. Foren. Med.(法医学杂志), 2013, (1): 43.
[38] LIANG Bao-liu, MAO Zhen-wei, LI De-hui, et al(梁宝鎏, 毛振伟, 李德卉, 等). Science in China Series B: Chemistry(中国科学(B辑化学)), 2003, (4): 340.
[39] YANG Yi-min, MAO Zhen-wei, ZHU Tie-quan, et al(杨益民, 毛振伟, 朱铁权, 等). Sciences of Conservation and Archaeology(文物保护与考古科学), 2003, (3): 1.
[40] LI He, DING Yin-zhong, DUAN Hong-ying, et al(李合, 丁银忠, 段鸿莺, 等). Sciences of Conservation and Archaeology(文物保护与考古科学), 2008, 20(4): 36.
[41] ZHU Tie-quan, WANG Chang-sui, MAO Zhen-wei, et al(朱铁权, 王昌燧, 毛振伟, 等). Rock Min. Anal.(岩矿测试), 2007, (5): 381.
[42] LING Xue, JIA Mai-ming, WEI Nü, et al(凌雪, 贾麦明, 魏女, 等). Journal of Northwest University·Natural Science Edition(西北大学学报 ·自然科学版), 2008, 38(1): 57.
[43] LI Qing-lin, WANG Ran, YAO Zheng-quan, et al(李清临, 王然, 姚政权, 等). Physical Testing and Chemical Analysis·Part B: Chemical Analysis(理化检验·化学分册), 2010, (8): 861.
[44] MA Yan-ying, ZHANG Jian-hua, HU Dong-bo(马燕莹, 张建华, 胡东波). Sciences of Conservation and Archaeology(文物保护与考古科学), 2015, 27(4): 50.
[45] LIANG Yue, ZHANG Zhi-fei(梁悦，张志飞). Acta Palaeontologica Sinica(古生物学报), 2018, 57(2): 202.
[46] CHEN Chao-fang, XU Cai-yun, PENG Bin, et al(陈朝方, 许彩芸, 彭彬, 等). J. Food Safe Qual.(食品安全质量检测学报), 2013, 44(4): 1046.
[47] WANG Yi-min(王毅民). Chinese J. Anal. Chem.(分析化学), 1992, 20(7): 850.
[48] WANG Yi-min, WANG Xiao-hong, GAO Yu-shu(王毅民, 王晓红, 高玉淑). Chinese J. Anal. Chem.(分析化学), 2001, 29(7): 845.
[49] WANG Yi-min, WANG Xiao-hong, GAO Yu-shu(王毅民, 王晓红, 高玉淑). Adv. Earth Sci.(地球科学进展), 2003, 18(3): 476.
[50] XU Tao, LUO Li-qiang(许涛, 罗立强). Rock Min. Anal.(岩矿测试), 2011, 30(3): 375.
[51] YAN Yi-ming, HE Ye-jun, DING Xun-liang, et al(颜一鸣, 赫业军, 丁训良, 等). Progress in Natural Science(自然科学进展), 2000, (11): 37.
[52] WANG Da-chun, YAN Yi-wu, HE Ye-jun, et al(王大椿, 颜一呜, 赫业军, 等). Journal of San Ming College(三明高等专科学校学报), 2003, (2): 11.
[53] TENG Yue-peng, SUN Tian-xi, LIU Zhi-guo, et al(滕玥鹏, 孙天希, 刘志国, 等). Acta Optica Sinica(光学学报), 2010, 2: 542.
[54] WANG Jun-jie, FU Ming-lei, LE Zi-chun(王俊杰, 付明磊, 乐孜纯). Opt. Instr.(光学仪器), 2014, 36(3): 239.
[55] YANG Jian, GE Liang-quan, ZHANG Bang, et al(杨健, 葛良全, 张邦, 等). Machine Design & Research(机械设计与研究), 2009, (2): 90.