1. 北京科技大学冶金与材料史研究所，北京 100083
2. UCL Institute of Archaeology, London, WC1H 0PY，UK
3. 河南省文物考古研究院，河南 郑州 450000
Scientific Research of Bimetallic Objects Unearthed from M2009 in the Guo State Cemetery at Sanmenxia
WANG Ying-chen1, LIU Ya-xiong1, 2, JIANG Tao3, CHEN Kun-long1*
1. Institute of History of Metallurgy and Materials, University of Science and Technology Beijing, Beijing 100083, China
2. UCL Institute of Archaeology, London, WC1H 0PY, UK
3. Henan Provincial Institute of Archaeology and Cultural Relics, Zhengzhou 450000, China
Abstract：The bronze-iron bimetallic objects unearthed from the Guo State Cemetery in Sanmenxia City are evidences of early use of iron in China’s Central Plains areas. This paper carries out scientific analyses of 3 bimetallic objects from tomb No. 2009 of this cemetery using metallography microscopy, Scanning Electronic Microscope-Energy Dispersive X-ray Spectroscopy (SEM-EDS) and Electron Microprobe (EMPA). It is revealed that the iron blade of spear head (STG001) was made of bloomery iron. Multiple-phased inclusions of silicate and iron oxide were elongated during the manufacturing process and arrayed along the deformation directions. Residue iron pills in the knife (SGT002) and the Ge Blade (SGT003) were found to be content notable Ni and a few of Co, and the result of line scanning analyses by the SEM-EDS shows interval distribution of nickel among different phase, indicating the meteoritic origin of the iron metal used to make the blades. The original Ni content of the meteoritic iron would fall in the ranges of IIIC and IIID types which will give the meteorites a microstructure of Finest (Off) or Ataxite. Metallography of bronze part of samples SGT001 and SGT 002 were observed to be typical as-casting microstructure of tin bronze with corroded α solid solution matrix and dispersed particles of (α+δ) eutectoid. The fact that there is no sign of deformation and recrystallization at the interface of iron and bronze parts indicates no further mechanical processing had been applied in the joint region. It is then inferred that the pre-made iron blades by were embedded into the casing mould and connected with bronze part by a cast-on process. On the basis of analytical results, this paper also briefly reviews the early use of iron metal in China and points out that the co-occurrence of meteoritic and manmade iron in the Guo State Cemetery demonstrated that this period had been a crucial stage in the development of iron metallurgy in China. The Northwest Region of China had played an important role during the transmission of early bloomery iron metallurgy while the establishment of cast iron technology in China’s Central Plains area would have a close relationship with the pre-existed technological tradition of bronze casting during the Shang and Zhou Periods.
Key words：History of metallurgy; Bronze-iron bimetallic object; Meteoric iron; Bloomery iron; Origin of iron metallurgy in China
王颖琛，刘亚雄，姜 涛，陈坤龙. 三门峡虢国墓地M2009出土铁刃铜器的科学分析及其相关问题[J]. 光谱学与光谱分析, 2019, 39(10): 3154-3158.
WANG Ying-chen, LIU Ya-xiong, JIANG Tao, CHEN Kun-long. Scientific Research of Bimetallic Objects Unearthed from M2009 in the Guo State Cemetery at Sanmenxia. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(10): 3154-3158.
[1] HAN Ru-bin, JIANG Tao, WANG Bao-lin(韩汝玢, 姜 涛, 王保林). Identification and Study of Iron Blade Bronzes from the Guo Cemetery(虢国墓出土铁刃铜器的鉴定与研究). In: Guo Cemetery at Sanmenxia(三门峡虢国墓). Beijing: Cultural Relics Press(北京: 文物出版社), 1999. 559.
[2] Scott E, Wasson J. Reviews of Geophysics，1975, 13(4): 527.
[3] CHEN Jian-li, MAO Rui-lin, WANG Hui, et al(陈建立, 毛瑞林, 王 辉, 等). Cultural Relics(文物)，2012, (8): 45.
[4] TANG Ji-gen(唐际根). Archaeology(考古)，1993, (6): 536.
[5] CHEN Jian-li(陈建立). New Exploration on the Metallurgy and Civilization in Ancient China(中国古代金属冶铸文明新探). Beijing: Science Press(北京：科学出版社), 2014.
[6] Guo W. From western Asia to the Tianshan. Mountains: on the Early Iron Artefacts Found in Xinjiang. In: Metallurgy and Civilisation: Eurasia and Beyond. London: Archtype Publication，2009. 107.
[7] CHEN Jian-li, YANG Jun-chang, SUN Bing-jun，et al(陈建立, 杨军昌, 孙秉君, 等). Science China Technological Sciences（中国科学: 技术科学)，2009, (9): 1574.
[8] HAN Ru-bin, KE Jun(韩汝玢, 柯 俊). History of Science and Technology in China·Mining and Metallurgy(中国科学技术史·矿冶卷). Beijing: Science Press(北京: 科学出版社), 2007.
