Sr2-x-yAl2SiO7∶x%Sm3+, y%Li+荧光粉的合成与发光特性研究

doi:10.3964/j.issn.1000-0593(2019)04-1013-05

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摘要：硅铝酸盐由于其化学性质稳定、原材料易得，是发光材料的一种有效基质，所以受到广泛关注。其中，硅铝酸锶(Sr₂Al₂SiO₇)属于四方晶系，具有稳定的晶体学结构。Sm³⁺作为一种常用的激活剂，其特征峰在波段300~750 nm内都有分布，有些特征激发峰位于近紫外光区，在近紫外区有强的吸收。因此，以Sr₂Al₂SiO₇为基质、Sm³⁺为激活剂可以制备出符合LED要求的红色荧光粉。本工作采用高温固相法合成一系列Sr_2-x-yAl₂SiO₇∶x%Sm³⁺, y%Li⁺荧光粉。通过X射线衍射(XRD)、光致荧光光谱(PL)、绝对量子效率测量系统对样品的晶体结构、发光特性以及内量子效率进行表征和测量，并且对样品的XRD进行精修，色纯度计算。结果表明：合成样品均为单相Sr₂Al₂SiO₇，掺杂Sm³⁺和电荷补偿剂Li⁺后，没有引起相变。相对于其他阳离子Sm³⁺(r=1.079 Å)、Li⁺(r=0.920 Å)的半径与Sr²⁺(r=1.260 Å)半径最为相近，因此更容易替代Sr²⁺的格位，并且两种离子半径比Sr²⁺小而使得样品晶体结构参数a，b，c和v逐渐减小。样品的最佳激发峰在403 nm处，相比于Ca₃Y₂(Si₃O₉)₂∶Sm³⁺的激发峰出现了3 nm蓝移，表明样品在近紫外光下有较强的吸收，这种长紫外波长的光有利于在照明领域的应用。在403 nm近紫外光激发下，可以看出，在500～750 nm范围内，Sm³⁺的发射峰位于564 nm(⁴G_5/2→⁶H_5/2)，601 nm(⁴G_5/2→⁶H_7/2)，648 nm(⁴G_5/2→⁶H_9/2)和713 nm(⁴G_5/2→⁶H_11/2)，其中601 nm发射峰强度最大，使样品呈现强烈的橙红色光。发射峰在607与618 nm处出现劈裂现象，是因为晶体场的相互作用引起了能级劈裂。单掺Sm³⁺的发射光谱强度随着浓度的增加先增大后减小，当掺杂浓度为2%时发光强度最大。利用Blasse提出的能量传递临界距离公式，计算得出临界距离R_C≈19.734 Å，从而说明了浓度猝灭原因是Sm³⁺之间的多级相互作用。根据Dexter理论，计算出多极相互作用函数θ≈6，表明Sr_2-xAl₂SiO₇∶x%Sm³⁺的浓度猝灭机理是电偶极-电偶极(d-d)相互作用。为进一步提高发光强度，掺杂了电荷补偿剂Li⁺，使晶体内部电荷达到平衡。实验结果表明，Li⁺最佳掺杂浓度为2%，与未加入电荷补偿剂相比，发光强度提高了2倍并测试其内量子效率为43.6%。荧光粉色坐标均在(0.60，0.39)附近，位于橙红色区域，具有较高色纯度(约92.2%)。该荧光粉在三基色白光LED中的红色成分有应用潜力。

关键词：Sr₂Al₂SiO₇∶Sm³⁺；Li⁺；电荷补偿剂Li⁺；橙红色荧光粉

Abstract：At present, aluminosilicates have attracted extensive attention because of their stable chemical properties and easy availability of raw materials, which have become an effective substrate for luminescent materials. Among them, barium aluminosilicate (Sr₂Al₂SiO₇) belongs to the tetragonal system and has a stable crystal structure. As a commonly used activator, Sm³⁺ has characteristic peaks distributed in the band of 300~750 nm. Some characteristic excitation peaks are located in the near-ultraviolet region and have strong absorption in the near-ultraviolet region. Therefore, using Sr₂Al₂SiO₇ as a matrix and Sm³⁺ as an activator, a red phosphor meeting the LED requirements can be prepared. In this work, a series of Sr_2-x-yAl₂SiO₇∶x%Sm³⁺, y%Li⁺ phosphors were synthesized by high temperature solid phase method. The crystal structure, luminescence properties and internal quantum efficiency of the sample were characterized and measured by X-ray diffraction (XRD), photoluminescence spectroscopy (PL), and absolute quantum efficiency measurement system, and the XRD of the sample was refined and the color purity was calculated. The results show that the synthesized samples are all single-phase Sr₂Al₂SiO₇, and do not cause phase transformation after doping with Sm³⁺ and charge compensator Li⁺. Relative to the other cations Sm³⁺(r=1.079 Å), Li⁺(r=0.920 Å) and the radius of Sr²⁺(r=1.260 Å) are the closest, so the two ions are more easily substituted for the Sr²⁺grid. The two ionic radius is smaller than Sr²⁺ to reduce the crystal structure parameters a, b, c and v of the sample. The best excitation peak of the sample is at 403 nm, which shows a blue shift of 3 nm compared to the excitation peak of Ca₃Y₂(Si₃O₉)₂∶Sm³⁺, indicating that the sample has strong absorption under near-ultraviolet light. That is beneficial for applications in the field of lighting. Under the excitation of 403 nm near-ultraviolet light, it can be seen that the emission peak of Sm³⁺ ions is located at 564 nm (⁴G_5/2→⁶H_5/2) and 601 nm (⁴G_5/2→⁶H_7/2) in the range of 500～750 nm. ), 648 nm (⁴G_5/2→⁶H_9/2) and 713 nm (⁴G_5/2→⁶H_11/2), of which the intensity of the 601 nm emission peak is the largest, which makes the sample appear strong orange red color. The emission peaks are cleaved at 607 and 618 nm because the interaction of the crystal fields causes energy level splitting. The intensity of the emission spectrum of the single-doped Sm³⁺ increases first and then decreases with the increase of the concentration, and reaches the strongest when the doping concentration is 2%. Using the energy transfer critical distance formula proposed by Blasse, the critical distance R_C≈19.734 Å is calculated, which indicates that the concentration quenching is caused by the multi-level interaction between Sm³⁺ ions. According to the Dexter theory, the multipole interaction function θ≈6 is calculated, indicating that the concentration quenching mechanism of Sr_2-xAl₂SiO₇∶x%Sm³⁺ is an electric dipole-electric dipole (d-d) interaction. In order to further increase the luminescence intensity, the charge compensator Li⁺ is doped to balance the internal charge of the crystal. The experimental results show that the optimum doping concentration of Li⁺ is 2%, and the luminescence intensity is increased by 2 times compared with the absence of charge compensator, and the internal quantum efficiency is tested to be 43.6%. Fluorescent pink coordinates are in the vicinity of (0.60, 0.39), located in the orange-red region, with a higher color purity (about 92.2%). The phosphor has potential applications in the red component of trichromatic white LEDs.

Key words：Sr₂Al₂SiO₇∶Sm³⁺; Li⁺; Charge compensator Li⁺; Orange red phosphor

收稿日期: 2018-09-01 修订日期: 2019-01-15

中图分类号:

O433.4

基金资助: 国家自然科学基金项目(11464045)，新疆师范大学教育厅重点实验室招标课题（KWFG1704）资助

通讯作者: 艾尔肯·斯地克 E-mail: aierkenjiang@sina.com

作者简介: 王庆玲，女，1992年生，新疆师范大学物理与电子工程学院硕士研究生 e-mail： 284997075@qq.com

引用本文:

王庆玲，迪拉热·哈力木拉提，沈玉玲，何久洋，艾尔肯·斯地克. Sr_2-x-yAl₂SiO₇∶x%Sm³⁺, y%Li⁺荧光粉的合成与发光特性研究[J]. 光谱学与光谱分析, 2019, 39(04): 1013-1017.
WANG Qing-ling, Dilare Halimulati, SHEN Yu-ling, HE Jiu-yang, Aierken Sidike. Synthesis and Luminescence Properties of Sr_2-x-yAl₂SiO₇∶x%Sm³⁺, y%Li⁺ Phosphors. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(04): 1013-1017.

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https://www.gpxygpfx.com/CN/10.3964/j.issn.1000-0593(2019)04-1013-05 或 https://www.gpxygpfx.com/CN/Y2019/V39/I04/1013